Synthesis and Characterization of Hydroxyapatite-Alumina biocomposite fabricated by Powder Metallurgy /
Taimur Sultan
- 92p. Soft Copy 30cm
Hydroxyapatite (HAP) is a very promising bio-ceramic as it resembles the mineral composition of bones and has excellent capability of bonding to bone tissues. It offers high biocompatibility, nontoxicity and good osteoconductivity. Therefore, it is an excellent choice for use as a bone substitute and in orthopedic or dental implants etc. However, its use is limited in biomedical applications specifically load-bearing implants as HAP exhibits poor mechanical properties. Alumina, known for its excellent mechanical strength and chemical stability, is added in HAP to enhance the mechanical properties of the composite while maintaining biocompatibility. The objective of this research is to synthesize and characterize a modified bio-composite with enhanced mechanical properties and excellent biocompatibility. For this purpose, an AluminaHAP bio-composite is developed with varying weight percent (wt. %) of Alumina. Two different processing routes, planetary ball mill which is high energy ball milling (HEBM) and tumbler ball milling i.e. low energy ball milling (LEBM), are adopted to mix the powders, and their impact on the mechanical properties is studied. The samples were prepared by using powder metallurgy techniques such as cold compaction followed by high temperature vacuum sintering process. The microstructure analysis is carried out using characterization techniques such as XRD, SEM etc. Mechanical testing of the samples is performed to compare the mechanical properties including density, hardness and compression strength of the sintered samples. The experimental results indicate that mechanical alloying using high-energy ball milling technique has significantly improved mechanical properties. Moreover, the mechanical properties of the bio-composite enhance with addition of Alumina (Al2O3) with the best results found for composite consisting of 40%HAP-60%Alumina. Overall, this research contributes towards the understanding of bio-composite materials for biomedical applications and the potential of HAP-Alumina bio-composite developed via Powder Metallurgy as a promising material for orthopedic and dental applications.